Search results for " deep eutectic solvents."
showing 5 items of 5 documents
Application of a low transition temperature mixture for the dispersive liquid–liquid microextraction of illicit drugs from urine samples
2021
© 2021 by the authors.
SINTESI STEREOSELETTIVA IN IONO-EUTECTOGEL SUPRAMOLECOLARI
2021
Systematic Synthesis and Properties Evaluation of Dicationic Ionic Liquids, and a Glance Into a Potential New Field
2018
Dicationic ionic liquids (DILs), a subset of the ionic liquid (IL) family, have attracted growing interest in recent years, and the range of applications within which they are investigated is constantly expanding. However, data which allows structure to property correlation of a DIL is still limited, and thus selecting an appropriate salt to address a specific challenge can be problematic. In comparison to traditional ILs, DILs physico-chemical properties can be tuned by changing the length and type of spacer which connects the cationic heads as well as the type of cation. This in turn could give rise to symmetrical or asymmetrical DILs. In this work, a systematic study of a homogeneous cla…
DEEP EUTECTIC SOLVENTS E LIQUIDI IONICI: SOLVENTI PER LO SVILUPPO DI PROCESSI ECO-COMPATIBILI
2020
L’obiettivo di questi tre anni di Dottorato è stato lo studio e l’utilizzo nuovi solventi di reazione in grado di sostituire i solventi organici classici. In particolare sono stati studiati i Deep Eutectic Solvent (DES) e le miscele di Liquidi Ionici (IL). I DES sono stati utilizzati come solventi per lo studio di reazioni organiche, usate per la formazione di nuovi legami C-C. Nello specifico sono state studiate la reazione di Diels-Alder, e diverse reazioni di coupling C-C catalizzate da Pd. In seguito, i DES sono stati utilizzati per la formazione di nuovi gel supramolecolari, chiamati eutectogel. Questi gel sono stati formati usando come gelator amminoacidi naturali, consentendo quindi …
Polysaccharide-based supramolecular bicomponent eutectogels as sustainable antioxidant materials
2023
In this work, we obtained supramolecular gels in deep eutectic solvents (DES) from polysaccharides like chitosan and chitosan : cellulose composites. We thoroughly characterized our gels by determining the minimum gelation concentration, as well as their porosity and swelling. We also investigated their mechanical properties by rheology, and morphology by scanning electron measurements. These properties were mainly influenced by the number of hydrogen bond sites on the hydrogen bond donor, (HBD), while FTIR-ATR investigation suggested that, upon gelation, cholinium cations interpose between polysaccharide chains affecting interchain hydrogen bonding. Our gels also exhibited self-healing and…